Button has selected a number of the company's models, including the Wraith, Phantom Drophead Coupe and Ghost, to transport him in style for ten of this year's grands prix.
"I am absolutely delighted to be accompanied by the very best in British luxury as I travel the world this year. I especially look forward to driving the Wraith, a fantastic addition to the Rolls-Royce fleet and quite simply a stunning car to look at and drive," said Button.
Richard Carter, Director of Global Communications, Rolls-Royce Motor Cars, added: "We feel privileged to provide a British icon with the consummate British car as he travels the world during the 2014 Grand Prix season.
"Jenson Button's commitment to success echoes Rolls-Royce's constant pursuit of perfection; we look forward to following his achievements and wish him the very best of luck."